Method of treating fish



March 18, 1952 J, RYAN METHOD 0F TREATING FISH 4 Sheets-Sheet l Filed Aug. 10, 1948 N RN s .W` Tfn:

ha@ @for a/iz J5? March 18, 1952 J. RYAN METHOD oF TREATING FISH 4 Sheets-Sheet 2 Filed Aug. lO, 1948 March 1,8, 1952 J. RYAN METHOD OF TREATING FISH 4 Sheets-Sheet 5 Filed Aug. l0, 1948 i f2s/7U@ @Z074 IZ j? M54? www March 18, 1952 1 RYAN 2,589,288

METHOD oF TREATING FISH Filed Aug. 1o, 1948 4 sheets-sheet 4 Patented Mar. 18, 1952 UNITED STATES PATENT OFFICE METHOD F TREATING FISH Application August 10, 1948, Serial No. 43,422

(Cl. {J9- 111) 12 Claims. 1

This invention relates to a method of effecting the complete recovery of all of the values contained in the various kinds of fish which are commercially caught and processed by the fish industry (either from salt Water or from fresh water sources) and to the new and improved products thus obtained.

In the fish industry, of course, the primary purpose is to obtain sh which may 4be used as food for human consumption. At the same time some sh may be caught which can not serve this purpose. Such fish, whether due to the species or to their condition, must be discarded and therefore constitute a waste. On the other hand, the edible fish in the course of being dressed for use have the edible portions removed, such as llets, steaks, cheeks, livers, oils and lights, and the remainder of the fish is discarded as waste material. A large proportion by weight of the iish caught by the fish industry, comprising whole fish of some species and the whole fish minus the edible portions of edible species, is accordingly unsuitable and incapable of being used as human food.

The recovery and treatment of fish and fish waste has heretofore been effected in various ways. It is a. common characteristic of all of such procedures of the prior art, however, that they are directed to the recovery of speciiic parts or components of the fish. Accordingly, the product is but a part of the iish.

Moreover, during such procedures, and in the nal product, the fish materials are subject to various mechanical conditions, making them difficult to handle or to store, and also susceptible to chemical and bacteriological conditions, such as putrefaction and the growth of bacteria and hence a source of pollution or contagion.

Some uses have been found for such fish wastes, as fertilizers, bait, or the like, but at such low values that a large proportion of that produced by the fish industry has been disposed of as a waste product only, often leading to offensive conditions or pollution of the surroundings. Special uses have also been found for certain selected parts of the fish, which have higher values accordingly, but these require particular procedures and are applicable only to such selected parts of the fish accordingly.

It is therefore an object of the .present invention to provide a method of treating whole sh and/or whole fish from which one or more of the edible components only, as set forth above, have been removed, whereby all of the components of the fish may be simultaneously and completely converted to a condition suitable for valuable commercial uses, substantially without loss and without necessity to discard any of it. There is, therefore, no ultimate waste by the present process, and all of the raw material may be converted to a single product.

It is also an object to convert such fish waste substantially to a liquid condition, and one having certain predetermined properties. In so doing, it is also an object to effect the conversion primarily by physical changes, with a minimum of chemical change of the components and without the addition of chemically reactive reagent materials.

It is a further object to convert fish waste into such a form and with such characteristic components and properties that it will lend itself economically to various commercial adaptations and uses, as new and improved productsv of the iish industry and other industries.

Other objects and accomplishments of the in- Vention will appear from the following disclosure.

By the present invention it is found that whole fish-that is to say all of the component parts of which fish are composed, whether solids, such as bones, scales, fins, flesh, viscera, etc., or liquids such as Water, oils, and the like-may be simultaneously and completely converted to a liquid condition so completely that there are substantially no residual solid particles in the resulting liquid product.

As a consequence, the entire catch of the fish industry, as a whole and/or in respect of the remainder left by the removal of any selected fraction of the several edible components, may be completely and simultaneously converted to liquid condition.

The product of applicants invention has therefore come to be known as liquid fish.

Liquid fish, a new term to the fish industry and also to the iish lay-products industries, relates to and designates a new product containing all of the components of whole fishor of whole sh minus one or more of the edible components for human consumption, only, namely the iiesh (fillets, steaks and cheeks), livers, oil and lightsin liquid condition and characterized by being substantially free from solids of larger particle size than that of colloids. (That is, not over 50 microns in diameter.)

The term liquid iish or liqueiied fish as used in the present specification and claims will be understood to have the meaning as set forth in the foregoing definition. A characteristic feature of liquid fish is that it is capable of uniform flow, and of standing, without segregation, and

that it will pass through a screen of 300 meshes per linear inch or a maximum particle size less than .050 mm.

This product may be obtained without mechanical disintegration or separation of the components of the raw fish and also without preliminary cooking operations which have in many instances been deemed to be necessary, though with large fish, such as cod and haddock, such mechanical steps are desirable. Moreover, the treatment is effected without the production of by-products at any stage of the process. The nal product is altogether inoffensive, per se, and not subject to deterioration in any way.

According to the process of the invention, therefore, whole fish, either as caught or after removal of selected edible portions only, as above set forth, are charged into a suitable closed container. The fish may be partially pre-cooked and/ or mechanically broken up, or not, as desired. Any air in the container is removed and the charge is heated gradually to the boiling point of water and above, under commensurate pressure, while venting the permanent gases, as through a relief valve. Thereby entrained air, absorbed, adsorbed or dissolved gases, and the like, are removed and expelled from the charge at an early stage of the operations. The heating up of the charge may be done indirectly, as by means of a steam jacket, but preferably directly as by the introduction of live steam into and throughout the charge. This also serves advantageously to agitate and disintegrate the charge. As such conditions of heat and increased pressure are developed and then maintained, the charge gradually becomes completely liqueed by conversion of the solid components of the fish to liquid form or condition, by dissolution or other interreactions of the components of the charge. Although .such conversion reactions are multifarious in kind and complex in character, they are effective upon all of the solid components of the fish to disintegrate the same and separate them, to a degree such that the sizes of substantially all of the components or ultimate reaction residues are of liquid consistency and either true liquids, in solution, or of substantially colloidal dimensions, or less. In other words, although there aresome residual solid ingredients of the fish, which are not liquefied or dissolved, they are present in minute ultimate dimensions and as the intervening or associated components become completely liquid, per se, or go into solution in the liquid reagent components of the charge, these solids are released and dispersed in substantially colloidal condition.

In consequence of such conversion, the charge as a whole is liquefied and the resulting liquid fish product may be removed from the reaction vessel or container by continuous flow. This may be effected either by gravity flow to a receiver below or by pumping upwardly to a receiver above the treating vessel and without segregation, clogging or adhesion to the surfaces of the conduits or other mechanisms employed. Moreover, the liquid fish may then be concentrated by appropriate evaporation and removal of its volatile liquid components to any predetermined degree of fluid concentration, Without loss of its characteristic liquid condition, or concentration may be carried further to a plastic condition and even to ultimate solidincation and complete dryness if this should be required or desired. In the latter forms it might be described as plasticf dried, or even solidified 4 liquid fish. But it is preferably maintained in its liquid condition, and with a concentration of total residual solids of 45% to 55% by weight, preferably, and at least 40% by weight.

The resulting product may be handled, stored and shipped with ease, and it may subsequently be readily employed for various purposes, but preferably in liquid form, for as such it may be handled and stored more readily and diluted as desired, without separation, if the pH value iS suitably maintained. However, it may be carried to solid condition (either by drying cr freezing) in which it is highly satisfactory for many uses and in conjunction with various other products.

By the present invention it is found that While the physical condition of the whole sh is thus rendered amenable to many subsequent treatments, its intrinsic values are conserved and preserved in its thus altered physical and chemical condition. The overall condition of the components of the fish as thus disintegrated and reduced to liquid form, is usually that of neutrality. Fresh fish give a pH value of about 6.5, While fish which have been kept or stored for an appreciable time may decompose somewhat. In the latter case, the pH value tends to rise to '7.5 or perhaps to 8.0 in some cases due to the formation or liberation of ammonia. Such variation from neutrality is not detrimental to the successful practice of the present method. But it may be desirable to offset such variation in the raw material and/ or in the finished product for purposes of storage and shipping, by adding appropriete alkalies such as caustic soda or sodium bicarbonate, or an acid, which may be organic, such as lactic acid, or inorganic, such as sulphuric, hydrochloric or phosphoric acid, or even to provide a pH value of 5 or slightly lower, for warm climates However, if neutral preservatives are added, such as common salt, such other additions or changes in the pH value of the product are not essential to its keeping qualities, nor for its satisfactory storage, distribution and use and the product may be slightly acidic or slightly basic though preferably neutral.

Moreover, it is found that by the present procedure, the inherent value of the components of the whole fish remain particularly undiminished. Especially is this true of the protein components and amino-acids contents of fish, which are high and which remain especially high in the liquid sh product obtained by the procedure of the present invention. This is true with respect to all of the proteinaceous amino-acids. Outstanding among these amino-acids is tryptophane, which is a vital component of food materials generally and which is found to remain substantially unaffected and undiminished by the conditions employed in the procedure of the present invention. In fact, the total value of the whole fish is found to be enhanced over that which is available in respect of its several separated components, and there is evidence of new values in the liquid fish which are not found in the separate components, such as the initial solids and water-soluble components, when used either separately or together. These new values are of the character of vitamin values and either manifest themselves in terms of enhanced vitamin potency of known vitamin values or constitute a new vitamin condition or component, per se.

For example, liquid fish, an account of its liquid and hence freely iiowing condition may be dispersed and disseminated as in the form of a spray, without segregation or separation of its S components. It may be thus mingled with feed materialsv of various kinds, such as dry poultry feeds, cattle feed and the like, whichA are usually finely ground, such as cereal grains, and may be similarly dispersed. In this Iway, finely divided droplets of liquid iish and dry powdery particles of `feed become intimately associated and accurately proportioned and combined. The combined resulting product is, moreover, of a high feed value in proteins, organic and mineral salts, and vitamin value, as well as in its carbohydrate content, with enhanced growth and fertility facv tors beyond the aggregate of the several components when prepared and used separately, as cereal feeds, fish meal and stickwater or press water.

A representative example of the invention will be described in its practical application in the fish industry, upon whole fish and/or whole fish from which the edible portions for human consumption have been removed, with reference to the accompanying drawings in which:

Fig. 1, which is divided into two parts l8L and 1b, is an elevational longitudinal layout of the complete sequence of units required for the proce ess, arranged from left to right in the order of progress of the fish therethrough. The fish are entered at the left, in the part la, and thence pass continuously to the right-hand end of le and thence from the left of 1b, therethrough to the storage tanks, at the right-hand end of lb, which receive the finished product;

Fig. 2 is an enlarged detail elevation and crosssection, with partsbroken away, of the digester in Fig. la, showing the level of the charge there- Fig. 3 is `an enlarged detail elevation and crosssection, with parts broken away, of the triple effect evaporator of Fig. 1b, showing the charge passing therethrough; and

Fig. 4 is an enlarged detail elevation and crosssection, with parts broken away, of the final evaporator, of Fig. 1b, showing the charge passing therethrough.

In the practical application of the process, the sh may be of various kinds or all of one kind,

, depending upon the daily catch. Moreover, the

charge may be of whole sh or Whole iish from which the edible portions only have been removed. On the other hand, the viscera may be removed, or both the edible portions and the viscereJ may be removed. In any event, all of the various characteristic components of the whole fish are present and are used.

This material may be dumped into the trough I (Fig. la) or onto the floor 2, from which the and may partially, but very slightly, pre-cook the sh. The time of passage is l0 to 20 minutes.

At the end of the chamber 9, the fish pass by gravity through a mechanical hog I6 which breaks up the fish when large, e. g., into pieces sufcient to pass a half inch mesh screen.

The resulting pulp falls into the surge chamber I1, from which it is handled as by conveyor I8 for delivery to subsequent operations of the process.

This preliminary heating or pre-cooking treatment may be omitted, especially with small fish or the remainders of fish which have been filleted, etc. Likewise the cutting up of the sh into smaller pieces may be omitted. But with large sh, such as cod, haddock and the like, it provides a convenient preliminary mechanical conditioning of the various fishes to size, consistency and uniformity of the charge. It also facilitates the preliminary wetting and admixture of the charge and the activity of the heat and steam upon the fresh fish.

As the charge of fish is drawn from the surge chamber I1 by conveyor IB, it is passed through a mixing chamber I9 by addition of water from the injector pump 20 if necessary. The charge of sh thus produced may be delivered into the line ZI (to charge a series of digestors, not shown, if desired) `but which is here shown as broken away, beyond the feed line 22. The latter is controlled by valve '23 and leads into the digestor 24, preferably at the top.

During introduction of the charge into the digester, the latter is subjected topartial vacuum screw conveyor 3, driven by motor 4, will carry it forward into the trough I, as the latter is emptied by the bucket elevator 5 driven by motor 6. Thus the fish are delivered indiscriminately but more or less uniformly into the hopper 1, at one end of the horizontal screw conveyor 8, mounted in the closed cylindrical chamber 9. The screw conveyor 8 is mounted on shaft IIJ which also has projecting vanes I I thereon and is driven by motor I2.

Beneath and parallel to the cylindrical chamber 9 is provided a steam line I3, connected to a series of manifolds I4, from which jets I'5 lead into the bottom of the otherwise closed charnber 9.

As the fish is thus charged into and along the closed chamber 9, live steam is introduced therein, and mixed with the fish sufliciently to heat (e. g. 15 vacuum) by means of the vacuum line 25 controlled by valve 26. In addition, a relief valve 21 may be provided.

The digester is provided with a stirrer shaft 28, driven by motor 29 and having agitating blades 3i) thereon at about the middle of the chamber and blades 3I at the bottom of the digester chamber. The bottom of the chamber is provided with a steam inlet and distributors 32 controlled by valve 33 from the steam pressure line 34, and an outlet sump 35, with valve 36.

With the valves 36 shut off, and the escape valve 21 open or the valve 26 open, or both, the

'pump I3 operates to deliver the charge of fish into the digester 2li until it is nearly full, as indicated by the dotted line. Valve 2G, if opened, may be then closed and the valvev 21 may be opened or left cracked as valve 23 is closed and steam is introduced through valve 33 and distributors 32 into the bottom of the charge, under pressure. In this way the charge is heated, any air or other gas in the digester is removed as the charge enters, and air dissolved or contained in the charge is expelled under the action of vacuum and heat, either into the vacuum line or through the cracked safety valve, as the case may be.

The digester may be advantageously covered with insulation, not shown, to reduce the amount of steam required to heat it and also to avoid the accumulation of resulting condensate in the charge. However, a considerable quantity of steam as well as air may be vented into the vacuum line and through the escape valve as the charge is brought up to temperature and pressure which is effected in about a half hour, e. g., to 275 to 285 F. or about 3l to 38 pounds per square inch gauge pressure.

This condition is developed and maintained, together with agitation of the charge, for about 3 or 4 hours, circulating it up around the sides and down through the middle of the digester,

' elevated temperature.

merely'V effectsftlieuniform "action of Ithe `steam*andpressure@throughout the charge. The

attrition, together with theagitated condition, heat, waterysteam, temperature v'and pressure, combined, Aeffect Athe dissolution of -lsubstantially all of the diversecomponents of the'sh, andso intimately vand completely that thes'mall proportion of ultimately insoluble matter which will not dissolveyorwhich is notliqueed, is'left in the smallstate of subdivision, in which it'originally occurs in the fish body and `structure, though u ni'edandbonded by the soluble and liquid or liqueable lcomponents which are liquefied'or dissolved and thusremoved therefrom in the digester.

Accordingly, by thus subjecting the entire charge of whole sh and all of the' components thereof simultaneously to attrition, steam, pressure'and agitation,`it is veffective to dissolve all of the soluble, 'liquid and liqueable components 'ously closed, and the valve 36 will be opened.

Thereupon the charge is passed from the sump 35 into the line 31 (Figs. 1a to 1b) through valve 38, strainer 39, valve 49 and pump 4L The pipe line 31 may be similarly connected with other digesters or a storage tank, not shown, to receive successive digested charges therefrom and deliver them to ehe evaporators.

The pump 4I serves to elevate and deliver the charge into the first effect 42 of a series of multiple eieet evaporators, of which three are here illustrated in series. As shownin greater detail in Fig. 3, the liquid fish is delivered into the evaporator at about themiddle point and brought to and maintained at this level during the evaporation operation, or the greater part of it (Fig. 3).

It will be observed that the charge, while in the digester, is under a positive pressure and at This fact, and theconsequent heat capacity of the charge, may be utilized to advantage in delivering the charge to the evaporator. While pumps are shown to effect the later stages of such transfer, the preliminary part of the discharge from the digester to the evaporator may be in large part accomplished by release of its own pressure by simply opening valves 36, 38 and 4B. The chamber of the rst effect may be at atmospheric pressure. Reduced pressure may be provided in the first eifect 42 of the evaporators (as a part of the vacuum system maintained throughout the evaporators) i. e., through the vacuumline 43leading from the first to the second effect 44, and thence Ythrough vacuum line 45 leading from the second effect to the third effect' 45 and thence to the vacuum outlet 41 to an actuated vacuum pump or the like, not shown.

In this way, the charge comingfrom the digester, in heated condition and under pressure, is subjected to a sudden reduction of pressure and consequently a drastic hashing effect in the rst effect evaporator, upon yadmission thereto, in which a large part of its water content is 'anduniformity of the charge.

"vapoiized, andiwithdrawn. Thus thepressure in the first effect "42 Yof :the V"evaporator system may be lat about atmospheric pressure, or slightly more, or considerably' lss, at the different stages or-throughout the transfer of the charge,'as desired. "The last part of the charge maybe withdrawn from `the digesterand cleared from the 'pipes-bypump 4I, whereupon the valve 40'will be closed.

The '-ch'arge, inthe'rst effect 42, is also subjected to-heat -by intro'ducing'steam through the steam'inlet 48 in to or through coil 49, havinga `-check valve 50. The coil`49 is submergedV in the charge. The Water 'of condensation inthe coil 49 isdrained olf through outlet 5|) At this stage of operations, the charge isvery fluid (consisting'of about 400 pounds of condensed steam -per ton of sh,l which are originally comoiffrom the bottom of the effect 42 may be opened, allowing the charge to ow (either continuously or inl batch operation) in to'the second effect of the evaporator 44. The charge enters at the'bottom-and comes to a level as indicated substantially at the same height as in the first effect. It submerges the steamcoiltherein whichis provided with inlet 56, check valve 51,

" and condensate return 58.

In the second effect 44 the effect of the vacuum line' 45 will also assist in the introduction of the charge as well as the slightly greater head from the' eect 42. In this effect, for example, the pressure may be reduced from that in the first effect to approximately Vlll of mercury. The temperatureV of the charge will also fall somewhat from-'the normal boiling point,e. g., to 180A F.

The heating'effectof vthe steam coil and evaporation of water vapor will maintain circulation The bale 59 will retain solids and liquid particles from escaping 'into the vacuum line 45.

Again, as the charge becomes concentrated, or

` as fresh charges are readyA for evaporation and introduction from the digesters, the valve 6D in the line' 6I leading from the bottom of the sec- 'ond effect 44 to the third effect 46 is opened, thus leading it into lthe bottom of the third effect and 60 again filling it to substantially the same level as vthe -first two effects. The steam coil 62 therein what lower temperature Ythanin the first two ef- "and greater evaporation effects, with corresponding concentration ofthe charge, a strrer 81 may vbe mounted'infthe bottom of the chamber, driven by the motor 68 through the shaft 69 passing through the packing chamber 10.

As the charge is thus progressively concentrated by evaporation and removal of its water content, and reaches the concentration desired, it may be withdrawn by opening valve 1l leading from the bottom of the chamber of the third effect 46 and thence into vthe line 12. If desired for any reason, such as a delay in the output of the digester and a desire to even up the level, or average the concentrations of the charges in the several effects, the valve 13 in` the line 12 leading back to the second effect 44, or the valve 14 leading back into the rst effect 42, or both, may be opened and the charge thus returned to the previous effects of the multiple effect evaporator by means of pump 15a or 15h suitably positioned in the line 12, and concentrated still further, likewise from effect 44 to effect 42.

But in the usual progressive operation of the process, the charge will be advanced continually or continuously through the line 12 by the pump 15 into the upper portion of an independent vacuum evaporator or unit 16 (Fig. 4) from which the vapors are withdrawn at the top through outlet 11 by an independent vacuum pump or the like, not shown, operated to develop such degree of vacuum therein as desired.

The evaporator 16 is provided with a sloping bottom 18 leading into the pump 19 which is adapted to circulate the charge into the lower portion lll) of a second vertical chamber 8l, substantially parallel to the evaporator 16, in which is mounted a steam coil 82, with inlet B3 and condensate outlet 84; The upper portion 85 of chamber 8l opens into the middle or upper portion of the evaporator chamber 16, through the wide passageway 86. The level of the charge as shown in preferably maintained sufciently above the steam coil 82 to cover the same and also sufciently high to flow freely through the passageway 86 into the evaporator 15. The pump 19 thus circulates the charge from the evaporator 16, upwardly through the steam coil 82 and back into the evaporator 16 through the passageway 86. The latter is provided with a baffle 81 to catch any entrained solid or liquid particles such as spray or fog and restrain its entry into the top of the evaporator and thus prevent its escape into the vacuum line 11, which may lead to a condenser or heat exchanger, not shown.

In the evaporator 16 the charge is evaporated to such consistency, specific gravity, total solids, surface tension and viscosity as may be desired.

l It is then withdrawn through outlet valve 88 in the bottom of the chamber 8! into the line 89 leading to the pump 90 (Fig. l) and thence through the valve 9| into the storage tank (or tanks) 92.

An outlet valve 93 may be provided from the storage tank $2 to the line 94 leading (in the direction of the arrow) to any appropriate means for ultimate use or delivery, not shown. Alternatively, however, it may be passed through valve Q back to the pump di, by which it may be led (or bled) back into the evaporator 42 and therein subjected to further evaporation and concentration, if this should for any reason be desired.

The conditions of the multiple eifect and final evaporators will be controlled in terms of the charge and of the properties of the product desired. Typically a vacuum of 18 of mercury in the final evaporator 16 and a temperature of about 170 F. may be maintained, for the required length of time to effect nal concentration.

to a sterilization treatment, and that from that point until the finished product is obtained, it is not subject to the action of bacteria or living organisms of any kind. Moreover, it is both liberated from air and other permanent gases, oxidizing or reducing. Side reactions and the formation of deteriorating by-products as well as putrefaction are thus positively prevented. Furthermore, in its nal finished condition, it is protected against any such subsequent changes or deterioration both mechanically and physically by its fluid condition and by its chemical condition and substantially neutral pH value.

As above described, the process is conducted with reference to sh which contain low contents of fats or oils, or in which such components, if present, are left as a part of the finished product. Fish which are of high fat or oil content may be advantageously thus processed, and the fats and oils left in the product. But it may be and usually is desirable to separate them. In this event, the same apparatus may be used and the same procedure followed. But it is then positively advantageous or necessary to employ the pre-cooking treatment or to extend it, in respect of time or temperature and pressure, or

both. To this end the permanent gases may be vented as at 96, or a relief pressure gauge may be provided so that the pre-cooking may be effected under increased steam pressure, free from inert gases such as air and superheated steam may be employed, if desired, to effect increased temperature, pressure, and/or evaporation upon the charge as it passes through the chamber 9. The treated and pre-cooked sh, reduced to small pieces if necessary in the hog at i6, may be then withdrawn from the surge tank I1 and subjected to pressing, centrifuging or like treatment to separate the `oil content. The remainder of the charge (solids and liquids) may then be returned to the process which is then continued and conducted from this stage on, as above described. The separated oil as thus recovered is of high Vitamin Value and content and in especially favorable condition, due to its substantially neutral condition, low heat treatment and nondestructive conditions of treatment of the sh relative to the reactive and sensitive characteristics of fish oils to physical and chemical deterioration.

The above described procedure is given in full detail as most conveniently carried out upon large fish, such as cod and haddock or the like. With these it is convenient, as indicated, to subject them to pre-cooking and/ or to subsequent reduction (in the hog) to pieces of about onehalf inch dimensions. This is especially desirable with sh which are both large and oily, so as to permit of separation of the oil at this stage, as above mentioned.

However, pre-cooking is not essential to the main process, and when it is conducted it should be restricted to effective temperatures only slightly above the boiling point of water and for a short time, preferably a few minutes only. A principal advantage of the pre-cooking is to raise the temperature of the fish so that when the fish goes to the digester the conditions of agitation, heat, steam and pressure will be the more active to attack and dissolve the most resistant components of the fish first-namely, the scales, fins, tails, and head structurewhich are both moist 1&1 and uniformly Warm or hot throughout such sur-faces;

It is' therefore to be understood that the fish, if non-oily or if the oil and fats are not to be separated, may be delivered directly into the digester 42 (Without preliminary heating, cooking or moistening), and the succeeding steps of the process carried out as above described successfully and satisfactorily.

Likewise, although a continuous process and suitable apparatus therefor has been described as the preferred and economically most advantageous adaptation of the invention, it is clear that it could be carried out in batch operations and even in separated stages as to time and place. Thus, the sh could be treated by pre-cooking, centrifuged to remove the oil and then stored, on the vessel in which they have been caught, and while at sea. They could then be subsequently digested and concentrated in a suitable plant ashore. Other adaptations will occur to those familiar with the fishing and by-product industries.

It is also to be understood that, for a more effective preliminary separation and recovery of thek oil or other liquid components, the fish may be pre-cooked or otherwise treated and then pressed to remove the liquid components from the solid components. The liquid components may then be separated, as by passing through a centrifuge to remove the oils or oils and fats, andy the residual aqueous and suspended solids fraction may be returned to and mixed with the solids components of the press cake. The resulting mixture may then be subjected to the succeeding steps of the process, as above described, by digesting, evaporating and concentrating, etc., as already set forth.

A typical product of liquid fish, prepared and concentrated in accordance with the procedure as above described, presents the following characteristics and properties:

Specific gravity at '75 F. from (1.15) to (1.26), averaging 1.20 to 1.24.

Viscosity-as determined in a Stormer torsion viscosimeter, with a 600 gram weight, at '75 F.- high, 150 revolutions per minute, low 260 revolutions per minute.

The particle size of the larger particles of suspended mineral matter are, as a matter of comparison, smaller than that of salt crystallized during the evaporation of soap lye, and of the order of colloidal dimensions and less, or else in liquid condition or in solution.

In deep sea fishing, which may involve rather prolonged voyages at sea, it is frequently necessary to carry out the dressing operation of removing the entrails of the fish and laying down the dressed sh on the vessel and While at sea. In such cases, the dressed fish are brought into port and the edible portions subsequently removed. When this is done, the remainder of the fish constitutes the whole fish minus both the edible portion and minus the viscera. The process may be carried out as above, but the product will thereupon correspond to liquid fish minus the constituents of the viscera as well as minus the edible portions.

It is especially to be observed that in reducing all of the components of sh simultaneously, not only are all possible proteins and allied compounds such as vitamins and amino-acids present in the charge which is subjected to the treatment, but such compounds are preserved without deterioration in quality or amount. This is, for example, the' casewith tryptophane, which is essential to the life processes and which is present in fish. Tryptophane remains substantially unaffectedA by the present process and hence is undiminished in the liquefied fish product obtained. In, consequence of' this fact, when the product is incorporated into feeds for poultry and thel like, they are greatly enhanced, not only in respect of promoting the growth factor of chickens fed therewith but egg production of hens and also a reduction in thefmorality factor of baby chicks.

In general, itis found that the method of the present invention effects thephysical disruption and disintegrationl of all of the solidl components of fish, promoting the dissolution of bothV the cellular contents and a large. part of the, connective tissue structures, andA appendages, such as the head, fins, tail, bones, etc., and the dispersion of the residual separated solid particles into very finely dividedY form. Moreover, it may be said that these changes are effected without pronounced chemicalv attack or alteration ofv the natural components of the fish, but primarily by a substantially neutral hydrolysis only, resulting in a product which possesses a higher total content and a higher content of each of the aminoacids, in or derivable from the natural proteins, severally, than is obtainable by a strongly acidic hydrolysis. The products of such neutral hydrolysis and disintegration are not only approximately neutral but retain substantially the initial molecular configuration of the proteins, (as nearly as is possible) and relatively free from combination with acidic or basic reactant radicals, which tend t9 be reactive Iwith the product or with other substances with which the product may later be associated, such as the apparatus, containers, air, feed materials and the like. The product is therefore unusually stable to normal conditions, has a high content of all of the food values which are inherent in freshly caught fish, and especially in respect of each and all of the amino-acids derivable from proteins, and is a valuable source for any or all of such values, per se, or by subsequent specific conversion or adaptation for specific purposes, as desired.

I claim:

1. Method of making liquefied fish, comprising the steps of subjecting all of the components of fish simultaneously tol contact with an atmosphere of steam at a pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately 50 microns.

2. Method of making liquefied fish, comprising the steps of subjecting all of the components of fish simultaneously to a temperature of at least about 275 F. and pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately 50 microns.

3. Method of making liquefied fish, comprising the steps of subjecting all of the components of fish simultaneously to a temperature of at least Vabout 275 F. and pressure of at least 30 pounds per square inch gauge pressure and at a pH Value of from 6.5 to 8.0 and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately 50 microns.

4. Method of making liquefied fish, comprising the steps of subjecting all of the components of fish simultaneously to a temperature of at least about 275 F. and pressure of at least 30 pounds per square inch gauge pressure and at a pH value of substantiall neutrality and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately 50 microns.

5. Method of making liqueiied iish, comprising the steps of subjecting all of the components of iish simultaneously to contact with an atmosphere of steam at a pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately 50 microns and subjecting the charge to Vacuum evaporation.

6. Method of making liquefied sh, comprising the steps of subjecting all of the components of iish simultaneously to contact with an atmosphere of steam at a pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately 50 microns and subjecting the charge to evaporation to a residual solids content of at least 40% by weight.

7. Method of making liquefied iish, comprising the steps of subjecting all of the components of iish simultaneously to contact with an atmosphere of steam at a pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately 50 microns and subjecting the charge to evaporation to a residual solids content of 45% to 55% by weight.

8. Method of making liqueed sh, comprising the steps of subjecting all of the components of the fish simultaneously to contact with an atmosphere of steam at a pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a colloidal condition.

9. Method of making liqueiied fish, comprising the steps of subjecting all of the components of the sh, minus edible portions only, simultaneously to contact with an atmosphere of steam at a pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a colloidal condition.

l0. Method of making liquefied sh, compriscontinuing these conditions until the charge is reduced substantially completely to a colloidal condition.

11. Method of making liquefied iish, comprising the steps of subjecting all of the components of the sh, minus edible portions only, simultaneously to a temperature of at least 275 F. and a pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately microns.

12. Method of making liquefied sh, comprising the steps of subjecting all of the components of the sh, minus edible portions and minus the viscera thereof, simultaneously to a temperature of at least 275 F. and at a pressure of at least 30 pounds per square inch gauge pressure and continuing these conditions until the charge is reduced substantially completely to a particle size below approximately 50 microns.

JOHN RYAN.

REFERENCES CITED The following references are of record in thev le of this patent:

UNITED STATES PATENTS OTHER REFERENCES Elementary Steam Power Engineering," 1923 edition by E. MacNaughton, page 89. Published by John Wiley & Sons, Inc., New York. 

